Analysis of 28 trace elements in the blood and serum antioxidant status in chickens under arsenic and/or copper exposure

Abstract

This study aimed to evaluate the 28 trace elements in the blood and serum antioxidant status in chickens under arsenic (As) and/or copper (Cu) exposure. A total of 200 1-day-old male Hy-Line chickens were fed either a commercial diet (C-group) or arsenic trioxide (30 mg/kg) and/or cupric sulfate (300 mg/kg) for 90 days. The 28 trace element levels in the blood were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The concentrations of As in the blood of chickens were elevated approximately 17.15-fold, 2.30-fold, and 13.37-fold in the As-group, Cu-group, and As + Cu-group, respectively, at 90 days. The concentrations of Cu did not change in the As-group and increased approximately 29.53 and 23.37% in the Cu-group and As + Cu-group, respectively, at 90 days. Moreover, As exposure caused ion profile disorders in the blood, including increased concentrations of Na, Mg, Si, K, Cr, Fe, and Se and reduced B, Ca, Ti, V, Mn, Co, Ni, Zn, Sr, and Mo. Cu exposure increased the contents of Mg, Si, Ca, Ti, V, Cr, Mn, Fe, Co, Zn, and Se and decreased the content of B, Ca, Al, Ni, and Mo. As + Cu exposure increased the contents of Mg, Si, Cr, Fe, Zn, and Se and decreased the content of B, Ca, Ti, Co, Ni, Sr, and Mo. Moreover, As and/or Cu exposure induced oxidative stress in the blood of chickens. In conclusion, the results indicated that the mixture of As and Cu caused a synergistic effect via disturbing homeostasis of trace elements and oxidative stress in the blood of chickens.

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Clausena anisata and Dysphania ambrosioides essential oils: from ethno-medicine to modern uses as effective insecticides

Abstract

Dysphania ambrosioides (L.) Mosyakin & Clemants (Amaranthaceae) and Clausena anisata (Willd.) Hook. f. ex Benth. (Rutaceae) are two aromatic species traditionally used in Cameroon to repel and kill insects. The present work was carried out to substantiate this traditional use and to evaluate the possible incorporation in commercial botanical insecticides of their essential oils (EOs). The EOs were distilled from leaves of C. anisata and aerial parts of D. ambrosioides and analyzed by gas chromatography-mass spectrometry (GC-MS). The insecticidal activity of both EOs was investigated against the filariasis vector, Culex quinquefasciatus, and the housefly, Musca domestica. As possible mode of action, the inhibition of acetylcholinesterase (AChE) by the two EOs was investigated as well. The D. ambrosioides EO was characterized by the monoterpene peroxide ascaridole (61.4%) and the aromatic p-cymene (29.0%), whereas the C. anisata EO was dominated by the phenylpropanoids (E)-anethole (64.6%) and (E)-methyl isoeugenol (16.1%). The C. anisata EO proved to be very toxic to third instar larvae of C. quinquefasciatus showing LC₅₀ of 29.3 μl/l, whereas D. ambrosioides EO was more toxic to adults of M. domestica showing a LD₅₀ of 51.7 μg/adult. The mixture of both EOs showed a significant synergistic effect against mosquito larvae with LC₅₀ estimated as 19.3 μl/l, whereas this phenomenon was not observed upon application to M. domestica adults (LD₅₀ = 75.9 μg/adult). Of the two EOs, the D. ambrosioides one provided a good inhibition of AChE (IC₅₀ = 77 μg/ml), whereas C. anisata oil was not effective. These findings provide new evidences supporting the ethno-botanical use of these two Cameroonian plants, and their possible application even in synergistic binary blends, to develop new eco-friendly, safe and effective herbal insecticides.

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Removal of industrial dyes and heavy metals by Beauveria bassiana : FTIR, SEM, TEM and AFM investigations with Pb(II)

Abstract

Presence of industrial dyes and heavy metal as a contaminant in environment poses a great risk to human health. In order to develop a potential technology for remediation of dyes (Reactive remazol red, Yellow 3RS, Indanthrene blue and Vat novatic grey) and heavy metal [Cu(II), Ni(II), Cd(II), Zn(II), Cr(VI) and Pb(II)] contamination, present study was performed with entomopathogenic fungi, Beauveria bassiana (MTCC no. 4580). High dye removal (88–97%) was observed during the growth of B. bassiana while removal percentage for heavy metals ranged from 58 to 75%. Further, detailed investigations were performed with Pb(II) in terms of growth kinetics, effect of process parameters and mechanism of removal. Growth rate decreased from 0.118 h⁻¹ (control) to 0.031 h⁻¹, showing 28% reduction in biomass at 30 mg L⁻¹ Pb(II) with 58.4% metal removal. Maximum Pb(II) removal was observed at 30 °C, neutral pH and 30 mg L⁻¹ initial metal concentration. FTIR analysis indicated the changes induced by Pb(II) in functional groups on biomass surface. Further, microscopic analysis (SEM and atomic force microscopy (AFM)) was performed to understand the changes in cell surface morphology of the fungal cell. SEM micrograph showed a clear deformation of fungal hyphae, whereas AFM studies proved the increase in surface roughness (RSM) in comparison to control cell. Homogenous bioaccumulation of Pb(II) inside the fungal cell was clearly depicted by TEM-high-angle annular dark field coupled with EDX. Present study provides an insight into the mechanism of Pb(II) bioremediation and strengthens the significance of using entomopathogenic fungus such as B. bassiana for metal and dye removal.

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Evaluating the toxic effects of three priority hazardous and noxious substances (HNS) to rotifer Brachionus plicatilis

Abstract

Hazardous and noxious substances (HNS) spill in the marine environment is an issue of growing concern, and it will mostly continue to do so in the future owing to the increase of high chemical traffic. Nevertheless, the effects of HNS spill on marine environment, especially on aquatic organisms are unclear. Consequently, it is emergent to provide valuable information for the toxicities to marine biota caused by HNS spill. Accordingly, the acute toxicity of three preferential HNS and sub-lethal effects of acrylonitrile on Brachionus plicatilis were evaluated. The median lethal concentration (LC₅₀) at 24 h were 47.2 mg acrylonitrile L⁻¹, 276.9 mg styrene L⁻¹, and 488.3 mg p-xylene L⁻¹, respectively. Sub-lethal toxicity effects of acrylonitrile on feeding behavior, development, and reproduction parameters of B. plicatilis were also evaluated. Results demonstrated that rates of filtration and ingestion were significantly reduced at 2.0, 4.0, and 8.0 mg L⁻¹ of acrylonitrile. Additionally, reproductive period, fecundity, and life span were significantly decreased at high acrylonitrile concentrations. Conversely, juvenile period was significantly increased at the highest two doses and no effects were observed on embryonic development and post-reproductive period. Meanwhile, we found that ingestion rate decline could be a good predictor of reproduction toxicity in B. plicatilis and ecologically relevant endpoint for toxicity assessment. These data will be useful to assess and deal with marine HNS spillages.

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Chemical characteristics and source analysis on ionic composition of rainwater collected in the Carpathians “Cold Pole,” Ciuc basin, Eastern Carpathians, Romania

Abstract

A study of precipitation chemistry was conducted for 11 years (01 January 2006–31 December 2016) in the Ciuc basin, Eastern Carpathians, Romania. The studied area is an enclosed basin, also called "the Carpathians cold pole." All collected samples were analyzed for major cations and anions. HCO₃⁻ concentrations were calculated based on the empirical relationship between pH and HCO₃⁻. The multiannual arithmetic mean of pH values was found to be 6.57. The lowest and highest pH values were measured in 2009 and 2013, being 6.57% lower, respectively, 7.57% higher than the multiannual mean. Only 3.31% of the studied rainwater samples indicate acidic character. In descending order, the majority of the samples are as follows: NH₄⁺ >Ca²⁺ >SO₄²⁻ >Cl⁻ >HCO₃⁻ >NO₃⁻ >Na⁺ >K⁺ >Mg²⁺ >NO₂⁻ >H⁺. Principal component analysis (PCA) showed the NH₄⁺, Ca²⁺, and Mg²⁺ contribution to the neutralization process and their sources. The anthropogenic origin of SO₄²⁻ was supported by the high non-sea-salt fraction (NSSF) (~ 91%). The results of this study suggest that rainwater chemistry is strongly influenced by local natural and anthropogenic sources (agricultural activities) rather than marine sources. The pollutants in rainwater samples were mainly derived from calcareous and dolomitic soil dust and specific local climatic conditions, long-range transport, local industry, and traffic sources.

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Identification of groundwater redox process induced by landfill leachate based on sensitive factor method

Abstract

Landfill site is a significant source of groundwater pollution. To ensure that the groundwater contamination of landfills can be controlled and repaired scientifically, the identification of groundwater pollution process is needed. On the basis of biogeochemical process of leachate pollutants in the groundwater environment, a sensitive factor method for the identification of groundwater redox process from landfills was established in this research. The method encompasses four phases, including sensitive factors selection, redox zone characterization, weight calculation, and redox zone identification. In the sensitive factor index system employed here, five indicators involving dissolved oxygen (DO), nitrite, Fe²⁺, sulfide, and CO₂ were selected. The boundary of each redox zones was determined by the quantitative method, and the weight of each indicator was calculated by combined weight method. This method was applied to a landfill site in the northeast of China. The result showed that there were five redox zones that appeared in pollution plume, including methanogenic zone (MGZ), sulfate reduction zone (SRZ), iron reduction zone (IRZ), nitrate reduction zone (NRZ), and oxygen reduction zone (ORZ). The results were consistent with the actual situation of the site. The sensitive factor method was scientific and effective to identify the groundwater redox process in landfill and can provide reference data related to investigation and remediation of groundwater pollution in landfill sites.

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Impact of bacterial ice nucleating particles on weather predicted by a numerical weather prediction model

Publication date: December 2017
Source:Atmospheric Environment, Volume 170
Author(s): Maher Sahyoun, Ulrik S. Korsholm, Jens H. Sørensen, Tina Šantl-Temkiv, Kai Finster, Ulrich Gosewinkel, Niels W. Nielsen
Bacterial ice-nucleating particles (INP) have the ability to facilitate ice nucleation from super-cooled cloud droplets at temperatures just below the melting point. Bacterial INP have been detected in cloud water, precipitation, and dry air, hence they may have an impact on weather and climate. In modeling studies, the potential impact of bacteria on ice nucleation and precipitation formation on global scale is still uncertain due to their small concentration compared to other types of INP, i.e. dust. Those earlier studies did not account for the yet undetected high concentration of nanoscale fragments of bacterial INP, which may be found free or attached to soil dust in the atmosphere. In this study, we investigate the sensitivity of modeled cloud ice, precipitation and global solar radiation in different weather scenarios to changes in the fraction of cloud droplets containing bacterial INP, regardless of their size. For this purpose, a module that calculates the probability of ice nucleation as a function of ice nucleation rate and bacterial INP fraction was developed and implemented in a numerical weather prediction model. The threshold value for the fraction of cloud droplets containing bacterial INP needed to produce a 1% increase in cloud ice was determined at 10⁻⁵ to 10⁻⁴. We also found that increasing this fraction causes a perturbation in the forecast, leading to significant differences in cloud ice and smaller differences in convective and total precipitation and in net solar radiation reaching the surface. These effects were most pronounced in local convective events. Our results show that bacterial INP can be considered as a trigger factor for precipitation, but not an enhancement factor.



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Isoprenoid emission variation of Norway spruce across a European latitudinal transect

Publication date: December 2017
Source:Atmospheric Environment, Volume 170
Author(s): Ylva van Meeningen, Min Wang, Tomas Karlsson, Ana Seifert, Guy Schurgers, Riikka Rinnan, Thomas Holst
Norway spruce (Picea abies) is one of the dominant tree species in the European boreal zone with the capacity to grow over large areas within Europe. It is an important emitter of biogenic volatile organic compounds (BVOCs), which can act as precursors of photochemical smog and ozone and contribute to the formation and growth of secondary organic aerosols (SOA) in the atmosphere.Isoprenoid emissions were measured from Norway spruce trees at seven different sites, distributed from Ljubljana in Slovenia to Piikkiö in Finland. Four of the sites were part of a network of genetically identical spruce trees and contained two separate provenances. The remaining three sites were part of other networks which have been used to conduct studies in the European boreal zone.There were minimal differences in the standardized emission rates between sites and across latitudes. The emission profile differed between provenances and sites, but there were not any distinct patterns which could be connected to a change in latitude. By using genetically identical trees and comparing the emission rates between sites and with genetically different trees, it was observed that the emission patterns were mostly influenced by genetics. But in order to confirm this possible stability of the relative emission profile based on genetics, more studies need to be performed.The effects of branch height, season and variation between years on observed emission pattern variations were also investigated. There were indications of potential influences of all three factors. However, due to different experimental setups between measurement campaigns, it is difficult to draw any robust conclusions.



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Overestimation of orthophosphate monoesters in lake sediment by solution 31 P-NMR analysis

Abstract

Solution ³¹P nuclear magnetic resonance spectroscopy (³¹P-NMR) is a useful method for analyzing organic phosphorus (P_o). Unfortunately, the extraction conditions, which are highly alkaline and require long extraction times, make this analysis less effective. In this research, according to the lability of orthophosphate monoesters (mono-P_o) and orthophosphate diesters (diesters-P_o), we verified the hypothesized overestimation of mono-P_o in lake sediment using solution ³¹P-NMR. We set three scenes to redistribute the mono-P_o and diesters-P_o. Six components, including eight mono-P_o species, were detected in the NaOH–EDTA extracts of sediment samples using ³¹P-NMR. The results showed that mono-P_o (212.7 mg kg⁻¹) was the dominant P_o in the surface sediment. In the three scenes, mono-P_o decreased from 212.7 to 112.0 mg kg⁻¹, and diesters-P_o increased from 31.9 to 132.7 mg kg⁻¹. The ratio of mono-P_o to diesters-P_o increased from 6.7 to 0.8. Therefore, we deduced that the concentration of mono-P_o was overestimated, while that of diesters-P_o was underestimated, in most research because of the high pH and long extraction process. Diesters-P_o might be an important labile P source during the P "exhausted" period.

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Inhibition of Phytophthora species, agents of cocoa black pod disease, by secondary metabolites of Trichoderma species

Abstract

Cocoa production is affected by the black pod disease caused by several Phytophthora species that bring, about each year, an estimated loss of 44% of world production. Chemical control remains expensive and poses an enormous risk of poisoning for the users and the environment. Biocontrol by using antagonistic microorganisms has become an alternative to the integrated control strategy against this disease. Trichoderma viride T7, T. harzanium T40, and T. asperellum T54, which showed in vivo and in vitro antagonistic activity against P. palmivora, were cultured and mycelia extracted. Inhibition activity of crude extracts was determined, and then organic compounds were isolated and characterized. The in vitro effect of each compound on the conidia germination and mycelia growth of four P. palmivora, two P. megakaria, and one P. capsici was evaluated. T. viride that displayed best activities produced two active metabolites, viridin and gliovirin, against P. palmivora and P. megakaria strains. However, no activity against P. capsici was observed. Besides being active separately, these two compounds have a synergistic effect for both inhibitions, mycelia growth and conidia germination. These results provide the basis for the development of a low-impact pesticide based on a mixture of viridin and gliovirine.

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Phytoremediation potential of moso bamboo ( Phyllostachys pubescens ) intercropped with Sedum plumbizincicola in metal-contaminated soil

Abstract

This study was conducted to investigate the capability of moso bamboo grown alone and in combination with Sedum plumbizincicola to remediate heavy metals. Monoculture of moso bamboo (MM), intercropping of moso bamboo × S. plumbizincicola (IMS), and control (uncultivated, CK) were established in Cu-, Zn-, and Cd-contaminated soil. Soil properties and heavy metal removal capacity were assessed. Results showed that the available and total heavy metal contents in soil (0–20 and 20–40 cm soil layers) were ranked IMS < MM < CK. Available Cu, Zn, and Cd contents were 65.0, 28.7, and 48.4% lower in the IMS and 52.8, 24.8, and 45.5% lower in the MM than those in the CK, respectively. In plants, Cu contents in bamboo rhizomes, branches, and leaves and those of Zn and Cd in all bamboo tissues were significantly higher in the IMS than in the MM. The bioconcentration and translocation factors of bamboo tissues showed an obviously increasing tendency from MM to IMS. Moso bamboo possessed the properties of endurance to heavy metals and high biomass production. Phytoremediation by moso bamboo in association with S. plumbizincicola is an economical strategy to promote heavy metal removal from metal-contaminated soil.

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Rapid biosynthesized AgNPs from Gelidiella acerosa aqueous extract mitigates quorum sensing mediated biofilm formation of Vibrio species—an in vitro and in vivo approach

Abstract

The present study explores the non-bactericidal anti-virulence efficacy of green synthesized silver nanoparticles (AgNPs) from Gelidiella acerosa against multi-drug resistant Vibrio spp. Spectral characterization of AgNPs was performed through UV-Visible, FT-IR, and energy-dispersive spectroscopic techniques followed by X-ray crystallography and zeta potential analysis. Further, the structural characterization was done by electron and atomic force microscopic techniques. AgNPs profoundly quelled the quorum sensing mediated violacein production in Chromobacterium violaceum and CV026. Characterized AgNPs at 100 μg mL⁻¹ concentrations depicted a phenomenal anti-biofilm efficacy against Vibrio parahaemolyticus (71%) and Vibrio vulnificus (83%) biofilms, which was further confirmed through light, confocal, and scanning electron microscopic analyses. In vitro bioassays revealed the remarkable inhibitory values of AgNPs, by inhibiting the exopolysaccharide production, hydrophobicity, and motility. In vivo studies using Artemia franciscana larvae also confirmed the anti-infective proficiency, as the AgNPs effectively reduced the bacterial colonization and enhanced the survival rate of larvae up to 100% without any toxicity effect.

Graphical abstract

Rapid biosynthesized AgNPs from Gelidiella acerosa quench quorum sensing controlled virulence traits in vibrios

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IJERPH, Vol. 14, Pages 1161: Higher Mortality in Trauma Patients Is Associated with Stress-Induced Hyperglycemia, but Not Diabetic Hyperglycemia: A Cross-Sectional Analysis Based on a Propensity-Score Matching Approach

IJERPH, Vol. 14, Pages 1161: Higher Mortality in Trauma Patients Is Associated with Stress-Induced Hyperglycemia, but Not Diabetic Hyperglycemia: A Cross-Sectional Analysis Based on a Propensity-Score Matching Approach

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101161

Authors: Cheng-Shyuan Rau Shao-Chun Wu Yi-Chun Chen Peng-Chen Chien Hsiao-Yun Hsieh Pao-Jen Kuo Ching-Hua Hsieh

Background: Stress-induced hyperglycemia (SIH) is a form of hyperglycemia secondary to stress and commonly occurs in patients with trauma. Trauma patients with SIH have been reported to have an increased risk of mortality. However, information regarding whether these trauma patients with SIH represent a distinct group with differential outcomes when compared to those with diabetic hyperglycemia (DH) remains limited. Methods: Diabetes mellitus (DM) was determined by patient history and/or admission glycated hemoglobin (HbA1c) ≥6.5%. Non-diabetic normoglycemia (NDN) was determined by a serum glucose level &lt;200 mg/dL in the patients without DM. Diabetic normoglycemia (DN) was determined by a serum glucose level &lt;200 mg/dL in the patients with DM. DH and SIH was diagnosed by a serum glucose level ≥200 mg/dL in the patients with and without DM, respectively. Detailed data of these four groups of hospitalized patients, which included NDN (n = 7806), DN (n = 950), SIH (n = 493), and DH (n = 897), were retrieved from the Trauma Registry System at a level I trauma center between 1 January 2009 and 31 December 2015. Patients with incomplete registered data were excluded. Categorical data were compared with Pearson chi-square tests or two-sided Fisher exact tests. The unpaired Student's t-test and the Mann–Whitney U-test were used to analyze normally distributed continuous data and non-normally distributed data, respectively. Propensity-score-matched cohorts in a 1:1 ratio were allocated using NCSS software with logistic regression to evaluate the effect of SIH and DH on the outcomes of patients. Results: The SIH (median [interquartile range: Q1–Q3], 13 [9–24]) demonstrated a significantly higher Injury Severity Score (ISS) than NDN (9 [4–10]), DN (9 [4–9]), and DH (9 [5–13]). SIH and DH had a 12.3-fold (95% confidence interval [CI] 9.31–16.14; p &lt; 0.001) and 2.4-fold (95% CI 1.71–3.45; p &lt; 0.001) higher odds of mortality, respectively, when compared to NDN. However, in the selected propensity-score-matched patient population, SIH had a 3.0-fold higher odd ratio of mortality (95% CI 1.96–4.49; p &lt; 0.001) than NDN, but DH did not have a significantly higher mortality (odds ratio 1.2, 95% CI 0.99–1.38; p = 0.065). In addition, SIH had 2.4-fold higher odds of mortality (95% CI 1.46–4.04; p = 0.001) than DH. These results suggest that the characteristics and injury severity of the trauma patients contributed to the higher mortality of these patients with hyperglycemia upon admission, and that the pathophysiological effect of SIH was different from that of DH. Conclusions: Although there were worse mortality outcomes among trauma patients presenting with hyperglycemia, this effect was only seen in patients with SIH, but not DH when controlling for age, sex, pre-existed co-morbidities, and ISS.

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IJERPH, Vol. 14, Pages 1162: Living Close to Natural Outdoor Environments in Four European Cities: Adults’ Contact with the Environments and Physical Activity

IJERPH, Vol. 14, Pages 1162: Living Close to Natural Outdoor Environments in Four European Cities: Adults' Contact with the Environments and Physical Activity

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101162

Authors: Margarita Triguero-Mas David Donaire-Gonzalez Edmund Seto Antònia Valentín Graham Smith David Martínez Glòria Carrasco-Turigas Daniel Masterson Magdalena van den Berg Albert Ambròs Tania Martínez-Íñiguez Audrius Dedele Gemma Hurst Naomi Ellis Tomas Grazulevicius Martin Voorsmit Marta Cirach Judith Cirac-Claveras Wim Swart Eddy Clasquin Jolanda Maas Wanda Wendel-Vos Michael Jerrett Regina Gražulevičienė Hanneke Kruize Christopher J. Gidlow Mark J. Nieuwenhuijsen

This study investigated whether residential availability of natural outdoor environments (NOE) was associated with contact with NOE, overall physical activity and physical activity in NOE, in four different European cities using objective measures. A nested cross-sectional study was conducted in Barcelona (Spain); Stoke-on-Trent (United Kingdom); Doetinchem (The Netherlands); and Kaunas (Lithuania). Smartphones were used to collect information on the location and physical activity (overall and NOE) of around 100 residents of each city over seven days. We used Geographic Information Systems (GIS) to determine residential NOE availability (presence/absence of NOE within 300 m buffer from residence), contact with NOE (time spent in NOE), overall PA (total physical activity), NOE PA (total physical activity in NOE). Potential effect modifiers were investigated. Participants spent around 40 min in NOE and 80 min doing overall PA daily, of which 11% was in NOE. Having residential NOE availability was consistently linked with higher NOE contact during weekdays, but not to overall PA. Having residential NOE availability was related to NOE PA, especially for our Barcelona participants, people that lived in a city with low NOE availability.

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IJERPH, Vol. 14, Pages 1163: Modeling of Chromium, Copper, Zinc, Arsenic and Lead Using Portable X-ray Fluorescence Spectrometer Based on Discrete Wavelet Transform

IJERPH, Vol. 14, Pages 1163: Modeling of Chromium, Copper, Zinc, Arsenic and Lead Using Portable X-ray Fluorescence Spectrometer Based on Discrete Wavelet Transform

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101163

Authors: Fang Li Anxiang Lu Jihua Wang

A modeling method based on discrete wavelet transform (DWT) was introduced to analyze the concentration of chromium, copper, zinc, arsenic and lead in soil with a portable X-ray fluorescence (XRF) spectrometer. A total of 111 soil samples were collected and observed. Denoising and baseline correction were performed on each spectrum before modeling. The optimum conditions for pre-processing were denoising with Coiflet 3 on the 3rd level and baseline correction with Coiflet 3 on the 9th level. Calibration curves were established for the five heavy metals (HMs). The detection limits were compared before and after the application of DWT, the qualitative detection limits and the quantitative detection limits were calculated to be three and ten times as high as the standard deviation with silicon dioxide (blank), respectively. The results showed that the detection limits of the instrument using DWT were lower, and that they were below national soil standards; the determination coefficients (R2) based on DWT-processed spectra were higher, and ranged from 0.990 to 0.996, indicating a high degree of linearity between the contents of the HMs in soil and the XRF spectral characteristic peak intensity with the instrument measurement.

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Modeling of yield and environmental impact categories in tea processing units based on artificial neural networks

Abstract

In this study, an artificial neural network (ANN) model was developed for predicting the yield and life cycle environmental impacts based on energy inputs required in processing of black tea, green tea, and oolong tea in Guilan province of Iran. A life cycle assessment (LCA) approach was used to investigate the environmental impact categories of processed tea based on the cradle to gate approach, i.e., from production of input materials using raw materials to the gate of tea processing units, i.e., packaged tea. Thus, all the tea processing operations such as withering, rolling, fermentation, drying, and packaging were considered in the analysis. The initial data were obtained from tea processing units while the required data about the background system was extracted from the EcoInvent 2.2 database. LCA results indicated that diesel fuel and corrugated paper box used in drying and packaging operations, respectively, were the main hotspots. Black tea processing unit caused the highest pollution among the three processing units. Three feed-forward back-propagation ANN models based on Levenberg-Marquardt training algorithm with two hidden layers accompanied by sigmoid activation functions and a linear transfer function in output layer, were applied for three types of processed tea. The neural networks were developed based on energy equivalents of eight different input parameters (energy equivalents of fresh tea leaves, human labor, diesel fuel, electricity, adhesive, carton, corrugated paper box, and transportation) and 11 output parameters (yield, global warming, abiotic depletion, acidification, eutrophication, ozone layer depletion, human toxicity, freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, terrestrial ecotoxicity, and photochemical oxidation). The results showed that the developed ANN models with R ² values in the range of 0.878 to 0.990 had excellent performance in predicting all the output variables based on inputs. Energy consumption for processing of green tea, oolong tea, and black tea were calculated as 58,182, 60,947, and 66,301 MJ per ton of dry tea, respectively.

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Polycyclic aromatic hydrocarbons in farmland soils around main reservoirs of Jilin Province, China: occurrence, sources and potential human health risk

Abstract

Study on the occurrence, sources and potential human health risk of polycyclic aromatic hydrocarbons in farmland soils around reservoirs is of great significance for the people drinking water security. In the present study, representative farmland soil samples around main reservoirs of Jilin Province, China, were investigated for 16 PAHs. The total concentrations of 16 priority PAHs in 32 farmland soil samples ranged from 602.12 to 1271.87 ng/g, with an arithmetic average of 877.23 ng/g, and the sum of seven carcinogenic PAH concentrations ranged from 30.07 to 710.02 ng/g, with a mean value of 229.04 ng/g. The 3-ring and 4-ring PAHs were major exist and account for 45.78 and 32.03%, respectively. Non-cancer and cancer risk of pollutants were calculated, and the results indicate that the complex PAHs in farmland soils were not considered to pose significant health effects. The isomer ratios Fla/(Fla + Pyr) and BaA/(BaA + Chr) show that the PAHs in soils were generally derived from biomass and coal combustion.

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IJERPH, Vol. 14, Pages 1159: Concentration Levels, Pollution Characteristics and Potential Ecological Risk of Dust Heavy Metals in the Metropolitan Area of Beijing, China

IJERPH, Vol. 14, Pages 1159: Concentration Levels, Pollution Characteristics and Potential Ecological Risk of Dust Heavy Metals in the Metropolitan Area of Beijing, China

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101159

Authors: Qiulin Xiong Wenji Zhao Jiayin Zhao Wenhui Zhao Lei Jiang

This study aims to investigate the concentration levels, pollution characteristics and the associated potential ecological risks of the heavy metals found in dust in the metropolitan area of Beijing, China during the winter. Dust samples were collected at 49 different spatial locations of Beijing's metropolitan area from November 2013 to January 2014, in which the concentration levels of Cd, Cr, Pb, Cu, Zn, Ni, Co, V, Bi and Mo were measured by Elan DRC II type inductively coupled plasma mass spectrometry (ICP-MS). Test results showed that the concentrations of dust heavy metals Pb, Cr, Cu and Zn in the urban areas (147.1 mg·kg−1, 195.9 mg·kg−1, 239.2 mg·kg−1 and 713.2 mg·kg−1) were significantly higher than those in the suburbs (91.6 mg·kg−1, 125.1 mg·kg−1, 131.9 mg·kg−1 and 514.5 mg·kg−1). Enrichment factors and the geo-accumulation index were used to describe the pollution characteristics of dust heavy metals in urban and suburban areas. Results indicated that Zn and Cu were moderately polluting in both urban and suburban areas, Cd was severely polluting in urban areas and heavily polluting in the suburbs. Furthermore, potential ecological risk assessment revealed that the degrees of ecological harm of dust heavy metals were very strong in both urban and suburban areas, but especially in urban areas. The potential ecological risk of heavy metal Cd, whose single factor of ecological damage was extremely strong, accounted for about 90% of the total ecological risk.

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IJERPH, Vol. 14, Pages 1157: Factors Affecting Transfer of Pyrethroid Residues from Herbal Teas to Infusion and Influence of Physicochemical Properties of Pesticides

IJERPH, Vol. 14, Pages 1157: Factors Affecting Transfer of Pyrethroid Residues from Herbal Teas to Infusion and Influence of Physicochemical Properties of Pesticides

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101157

Authors: Jin-Jing Xiao Yang Li Qing-Kui Fang Yan-Hong Shi Min Liao Xiang-Wei Wu Ri-Mao Hua Hai-Qun Cao

The transfer of pesticide residues from herbal teas to their infusion is a subject of particular interest. In this study, a multi-residue analytical method for the determination of pyrethroids (fenpropathrin, beta-cypermethrin, lambda-cyhalothrin, and fenvalerate) in honeysuckle, chrysanthemum, wolfberry, and licorice and their infusion samples was validated. The transfer of pyrethroid residues from tea to infusion was investigated at different water temperatures, tea/water ratios, and infusion intervals/times. The results show that low amounts (0–6.70%) of pyrethroids were transferred under the different tea brewing conditions examined, indicating that the infusion process reduced the pyrethroid content in the extracted liquid by over 90%. Similar results were obtained for the different tea varieties, and pesticides with high water solubility and low octanol–water partition coefficients (log Kow) exhibited high transfer rates. Moreover, the estimated values of the exposure risk to the pyrethroids were in the range of 0.0022–0.33, indicating that the daily intake of the four pyrethroid residues from herbal tea can be regarded as safe. The present results can support the identification of suitable tea brewing conditions for significantly reducing the pesticide residue levels in the infusion.

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IJERPH, Vol. 14, Pages 1158: Identification of Linkages between EDCs in Personal Care Products and Breast Cancer through Data Integration Combined with Gene Network Analysis

IJERPH, Vol. 14, Pages 1158: Identification of Linkages between EDCs in Personal Care Products and Breast Cancer through Data Integration Combined with Gene Network Analysis

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101158

Authors: Hyeri Jeong Jongwoon Kim Youngjun Kim

Approximately 1000 chemicals have been reported to possibly have endocrine disrupting effects, some of which are used in consumer products, such as personal care products (PCPs) and cosmetics. We conducted data integration combined with gene network analysis to: (i) identify causal molecular mechanisms between endocrine disrupting chemicals (EDCs) used in PCPs and breast cancer; and (ii) screen candidate EDCs associated with breast cancer. Among EDCs used in PCPs, four EDCs having correlation with breast cancer were selected, and we curated 27 common interacting genes between those EDCs and breast cancer to perform the gene network analysis. Based on the gene network analysis, ESR1, TP53, NCOA1, AKT1, and BCL6 were found to be key genes to demonstrate the molecular mechanisms of EDCs in the development of breast cancer. Using GeneMANIA, we additionally predicted 20 genes which could interact with the 27 common genes. In total, 47 genes combining the common and predicted genes were functionally grouped with the gene ontology and KEGG pathway terms. With those genes, we finally screened candidate EDCs for their potential to increase breast cancer risk. This study highlights that our approach can provide insights to understand mechanisms of breast cancer and identify potential EDCs which are in association with breast cancer.

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IJERPH, Vol. 14, Pages 1160: “It’s a Battle… You Want to Do It, but How Will You Get It Done?”: Teachers’ and Principals’ Perceptions of Implementing Additional Physical activity in School for Academic Performance

IJERPH, Vol. 14, Pages 1160: "It's a Battle… You Want to Do It, but How Will You Get It Done?": Teachers' and Principals' Perceptions of Implementing Additional Physical activity in School for Academic Performance

International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14101160

Authors: Vera van den Berg Rosanne Salimi Renate de Groot Jelle Jolles Mai Chinapaw Amika Singh

School is an ideal setting to promote and increase physical activity (PA) in children. However, implementation of school-based PA programmes seems difficult, in particular due to schools' focus on academic performance and a lack of involvement of school staff in program development. The potential cognitive and academic benefits of PA might increase chances of successful implementation. Therefore, the aim of this qualitative study was: (1) to explore the perceptions of teachers and principals with regard to implementation of additional PA aimed at improving cognitive and academic performance, and (2) to identify characteristics of PA programmes that according to them are feasible in daily school practice. Twenty-six face-to-face semi-structured interviews were conducted with primary school teachers (grades 5 and 6) and principals in The Netherlands, and analysed using inductive content analysis. Teachers and principals expressed their willingness to implement additional PA if it benefits learning. Time constraints appeared to be a major barrier, and strongly influenced participants' perceptions of feasible PA programmes. Teachers and principals emphasised that additional PA needs to be short, executed in the classroom, and provided in "ready-to-use" materials, i.e., that require no or little preparation time (e.g., a movie clip). Future research is needed to strengthen the evidence on the effects of PA for academic purposes, and should examine the forms of PA that are both effective as well as feasible in the school setting.

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Characterization of semen quality, testicular marker enzyme activities and gene expression changes in the blood testis barrier of Kunming mice following acute exposure to zearalenone

Abstract

A total of 95 8-week-old male Kunming mice were randomly assigned into five groups and exposed to zearalenone (ZEA) at doses of 25, 50, and 75 mg/kg delivered by intra-peritoneal (i.p.) injection for 5 days. The testis and epididymis indices involving sperm quality and morphology, testis enzyme activities, serum concentrations of testosterone and estrogen, and the expression levels of the three gene and protein of N-cadherin, vimentin, and claudin 11 related to the blood testis barrier (BTB) were analyzed. Results showed that ZEA significantly decreased body weight and semen quality compared to the control group along with increased activity of alkaline phosphatase (ALP), acid phosphatase (ACP), lactate dehydrogenase (LDH), and reduced serum concentrations of testosterone and estrogen. At the mRNA and protein levels, expression of N-cadherin, vimentin, and claudin 11 significantly increased; however, the mRNA and protein of N-cad expression decreased. These data suggest acute exposure to ZEA reduces sperm quality and significantly decreases the concentration of serum testosterone and estradiol. In addition, the activities of the testis marker enzymes and associated mRNA and protein expressions of the BTB were also significantly affected. Our results demonstrated that ZEA has a significant impact on the reproductive parameters of male mice which showed compensatory response to strengthen the barrier function of the BTB following ZEA exposure.

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Variation in foliar uptake of polycyclic aromatic hydrocarbons in six varieties of winter wheat

Abstract

To investigate intraspecific variations of foliar uptake of polycyclic aromatic hydrocarbons (PAHs) of winter wheat (Triticum aestivum L.), leaves of six varieties including Changwu 521 (CW), Hedong TX-006 (HD), Jiaomai 266 (JM), Xiaoyan 22 (XY), Yunong 949 (YN), and Zhongmai 175 (ZM) were exposed to three levels of (0, 0.25, and 1.5 mg L⁻¹) mixture of six selected PAHs (phenanthrene, anthracene, pyrene, benz[a]anthracene, benzo[a]pyrene, and benzo[g,h,i]perylene). After 10 consecutive days of application, all the six selected PAHs (Σ₆ PAHs) were determined in the leaves of the six varieties of the winter wheat. There were apparent intraspecific differences in foliar uptake of PAHs in the winter wheat. The highest concentrations of Σ₆ PAHs in the leaves of YN variety (64.6 mg kg⁻¹) were approximate two times of the lowest concentrations in the leaves of HD variety (29.6 mg kg⁻¹). Both individual PAHs and Σ₆ PAHs in the cuticular waxes were significantly (p < 0.01) higher than those in leaves and far higher than those in roots, indicating that the cuticular waxes could play significant role in foliar uptake of PAHs. The present results also showed that the concentrations PAHs in leaves were positively (p < 0.05) correlated with the water solubility of the six selected PAHs. In addition, the present study suggested that there was basipetal translocation of PAHs in the winter wheat after foliar application of PAHs, although the mechanism was yet to be further studied.

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The average concentration function of dissolved copper in Hun River, Liaoning province, Northeastern China

Abstract

Water samples were collected from Hun River to research the change in the concentration of dissolved copper and its distribution as well as accumulation during the dry season in 2013. The mean concentrations of dissolved copper in Hun River were 0.1057–0.1533 mg/l during the dry season. The results indicated that the most severe dissolved copper pollution were associated with the mining area, industrial area, and living area along the Hun River. The results also indicated that controlling the sources of copper pollution effectively reduced the concentration of dissolved copper in Hun River. The concentration function about time and spatial coordinate, average concentration function about time coordinate, average concentration function about spatial coordinate, and bounded mean oscillation space were used to evaluate the extent of copper pollution in Hun River. The error function, quartiles, and curve fitting tool were performed to determine the stations with high concentration of dissolved copper in Hun River. We furthermore obtained the upper and lower bounds of the error between two kinds of bounded mean oscillation spaces to explore the migration of copper pollution in Hun River. The results of the average concentration function and bounded mean oscillation space revealed that the long-term control measures of copper pollution and short-term control measures of copper pollution, the control of copper pollution in large watershed, and the control of copper pollution in small watershed in Hun River should be combined with each other. The strict policy and pollution control strategy should be implemented to ensure that the water of the Hun River meets the natural environment standard for the growth of aquatic life and human.

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Influence of rapid rural-urban population migration on riverine nitrogen pollution: perspective from ammonia-nitrogen

Abstract

China is undergoing a rapid transition from a rural to an urban society. This societal change is a consequence of a national drive toward economic prosperity. However, accelerated urban development resulting from rapid population migration from rural to urban lands has led to high levels of untreated sewage entering aquatic ecosystems directly. Consequently, many of these regions have been identified as hot spots of riverine nitrogen (N) pollution because of the increasing level of urban point-source discharge. In order to address this concern, we assessed effects of urban development on ammonia-nitrogen (AN) loads using a panel data regression model. The model, expressed as an exponential function of anthropogenic N inputs multiplied by a power function of streamflow, was applied to 20 subwatersheds of the Huai River Basin for the years 2003–2010. The results indicated that this model can account for 81% of the variation in annual AN fluxes over space and time. Application of this model to three scenarios of urban development and sewage treatment (termed urbanization priority, sustainable development, and environmental priority) suggests that future N pollution will inevitably deteriorate if current urban environmental management and investment are not significantly improved. Stronger support for environmental management is very critical to alleviate N pollution and improve water quality. More effort should focus on improving sewage treatment and the N removal rate of the current sewage system in light of the increasing degree of urbanization.

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Ειδοποίηση Μελετητή - [ "Περιβαλλοντικά προβλήματα" ]

Ειδοποίηση Μελετητή:[ "Περιβαλλοντικά προβλήματα" ]

Διαχείριση αποβλήτων πτηνοτροφικών-αυγοπαραγωγικών μονάδων. Αξιοποίηση αποβλήτων για την παραγωγή λιπασμάτων και ελαχιστοποίηση των επιπτώσεων στο …

Δ Παπαδόπουλος - 2017

... Ο όγκος τους, δεδομένης και της εντατικοποίησης της παραγωγής που παρατηρείται τα τελευταία
χρόνια λόγω της γενικότερης ανάπτυξης, παρουσιάζει αυξητική τάση και δημιουργεί σημαντικά
περιβαλλοντικά προβλήματα, τα οποία σε καμία περίπτωση δεν μπορούν πλέουν να ...

Η ΕΠΙΔΡΑΣΗ ΤΗΣ ΑΤΜΟΣΦΑΙΡΙΚΗΣ ΣΩΜΑΤΙΔΙΑΚΗΣ ΡΥΠΑΝΣΗΣ ΣΤΗ ΔΗΜΟΣΙΑ ΥΓΕΙΑ ΤΩΝ ΠΛΗΘΥΣΜΩΝ ΤΩΝ ΜΕΓΑΛΩΝ ΑΣΤΙΚΩΝ ΚΕΝΤΡΩΝ

Ε ΓΕΩΡΓΙΩΤΗ - 2017

... hospital admissions. Issue Date: 16-Sep-2017. Abstract: Η ατμοσφαιρική ρύπανση
αποτελεί ένα από τα σημαντικότερα περιβαλλοντικά προβλήματα που αντιμετωπίζει
εδώ και πολλές δεκαετίες η επιστημονική κοινότητα. Η συνεχής ...

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Αυτή η Ειδοποίηση του Μελετητή Google σας προσφέρεται από τη Google

Ακύρωση ειδοποίησης
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Ειδοποίηση Μελετητή - [ "κλιματική αλλαγή" ]

Ειδοποίηση Μελετητή:[ "κλιματική αλλαγή" ]

Εθνική Στρατηγική για την Προσαρμογή στην Κλιματική Αλλαγή στο πλαίσιο της Ευρώπης του 2020 με έμφαση στην Ενέργεια

Ν Βασιλάρας - 2017

Ο Σκοπός της παρούσας Δ. Ε είναι η καταγραφή από σήμερα μέχρι και το έτος 2020, της
Εθνικής Στρατηγικής για την προσαρμογή στην κλιματική αλλαγή στο πλαίσιο της Ευρώπης
του 2020 με έμφαση στην ενέργεια, καθώς και η ανάλυση των διαδικασιών που θα

Ενεργειακή Ασφάλεια και Κλιματική Αλλαγή στην Ελλάδα

Δ Μπεχλιβάνης - 2017

Η παρούσα διπλωματική εργασία συντάχθηκε στα πλαίσια του Μεταπτυχιακού
Προγράμματος σπουδών και έχει ως θέμα της «Ενεργειακή Ασφάλεια και Κλιματική Αλλαγή
στην Ελλάδα». Στόχος της εργασίας ήταν να συνδέσει δυο παραμέτρους που φαινομενικά δε

Η προσαρμογή των οδικών υποδομών στην κλιματική αλλαγή

Ι Καραγκιώζης - 2017

Η παρούσα διπλωματική εργασία εκπονήθηκε με στόχο να διερευνήσει τη δυνατότητα
προσαρμογής των οδικών υποδομών στην επερχόμενη κλιματική αλλαγή, διερευνώντας
στρατηγικές και πρακτικές από τη Διεθνή κοινότητα. Δεδομένου της σημαντικότητας του

Αξιοποίηση και σχεδιασμός συστημάτων πυρασφάλειας με τη χρήση επεξεργασμένων υγρών αποβλήτων

Μ Ζέρβα - 2017

... διεργασίες ή επιταχύνουν κάποιες άλλες. Είναι ευρέως γνωστό ότι η κλιματική αλλαγή
έχει αλλάξει τον παγκόσμιο χάρτη των δασικών πυρκαγιών, καθώς όλο και πιο συχνά
εμφανίζονται τέτοιου είδους φαινόμενα. Οι πυρκαγιές είναι ένα ...

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Αυτή η Ειδοποίηση του Μελετητή Google σας προσφέρεται από τη Google

Ακύρωση ειδοποίησης
Δημιουργία λίστας των ειδοποιήσεών μου

Ειδοποίηση Μελετητή - [ "Ατμοσφαιρική ρύπανση" : επιπτώσεις στην υγεία ]

Ειδοποίηση Μελετητή:[ "Ατμοσφαιρική ρύπανση" : επιπτώσεις στην υγεία ]

Η ΕΠΙΔΡΑΣΗ ΤΗΣ ΑΤΜΟΣΦΑΙΡΙΚΗΣ ΣΩΜΑΤΙΔΙΑΚΗΣ ΡΥΠΑΝΣΗΣ ΣΤΗ ΔΗΜΟΣΙΑ ΥΓΕΙΑ ΤΩΝ ΠΛΗΘΥΣΜΩΝ ΤΩΝ ΜΕΓΑΛΩΝ ΑΣΤΙΚΩΝ ΚΕΝΤΡΩΝ

Ε ΓΕΩΡΓΙΩΤΗ - 2017

... που συμβάλουν στην εξάπλωσή της, καθιστούν την ατμοσφαιρική ρύπανση ένα μείζονος ... ποιότητα,
καθώς επιδρούν αρνητικά στο περιβάλλον, την υγεία, τα φυσικά ... της κατώτερης τροπόσφαιρας
παρουσιάζει ιδιαίτερο ενδιαφέρον, εξαιτίας των επιπτώσεων της ατμοσφαιρικής ...

Τα επίπεδα των βαρέων μετάλλων στην ατμόσφαιρα αστικών και βιομηχανικών περιοχών στην Ελλάδα. Συγκρίσεις-συσχετίσεις με επίπεδα εκπομπών και συγκεντρώσεων …

Α ΓΙΑΝΤΣΙΟΥ - 2017

... Keywords: ατμοσφαιρική ρύπανση;air pollution;βαρέα μέταλλα;heavy metals;αιωρουμενα
σωματιδια;particulate matter. Issue Date: 16-Sep-2017. Abstract: Η μελέτη των βαρέων μετάλλων
στην ατμόσφαιρα και των επιπτώσεών τους στην υγεία του ανθρώπου και στο περιβάλλον ...

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Ecological risk assessment of heavy metals in salt-affected soils in the Natura 2000 area (Ciechocinek, north-central Poland)

Abstract

This paper aimed to evaluate the ecological risk posed by the accumulation of heavy metals in the salt-affected soils of the habitat covered by the EU Natura 2000 program in relation to the activity of soil redox enzymes. The research was carried out in the halophyte reserve in Ciechocinek (north-central Poland) which is a very specific habitat as it undergoes a long-term human impact related to both the operation of the medical spa town and the agricultural use of soils in the adjacent areas. The obtained results showed that the content of Zn, Cu, Pb, and Cd in the studied soils exceeded the Polish standards. Based on the obtained data and statistical analysis, it was found that metals may come from two different sources: emission from household boiler rooms (Pb, Cd) and corroded brine sewage pipeline (Zn, Cu).They are characterized by limited mobility due to alkaline environment and strong sorption properties of the clay fraction and organic matter. The correlation analysis indicates that the dehydrogenase activities were negatively correlated with soil electrical conductivity (EC_1:5) (r = − 0.665, P < 0.05). Taking into account the protective status of the area, it is difficult to indicate definitely the solution concerning the land management. However, according to the authors, one should pay special attention to a possibility of using halophytes which occur within the reserve for phytoremediation.

from Enviromental via alkiviadis.1961 on Inoreader http://ift.tt/2xEXIPW

Assessment and modeling of E-waste generation based on growth rate from different telecom companies in the State of Kuwait

Abstract

The present work assesses the production rate of cell phone e-waste in Kuwait by comparing the number of clients in three telecommunication service providers like Zain, Ooredoo, and Viva in the state of Kuwait over a period of 7 years from 2008 to 2015. An online survey was conducted to evaluate the growth in the number of clients in three cell phone companies, and the data analysis was carried out using statistical package for the social sciences (SPSS) software. The prediction of the growth percentage of the number of clients in each telecommunication company was analyzed using analysis of variance (ANOVA) test and followed by the regression model. The study shows that there is an increase in the number of clients in all three companies (Zain, Ooredoo, and Viva) between year 2008 and 2015, and it was estimated that approximately 7.9 million cell phone users would be achieved in the first quarter of 2015. Based on this predicted number of cell phone users, the production of e-waste would be 3 kt per year with an average growth of 12.7%.

from Enviromental via alkiviadis.1961 on Inoreader http://ift.tt/2x3POei

Impact of an invasive weed, Parthenium hysterophorus , on a pasture community in south east Queensland, Australia

Abstract

Parthenium weed is a highly invasive alien species in more than 40 countries around the world. Along with severe negative effects on human and animal health and crop production, it also causes harm to ecosystem functioning by reducing the native plant species biodiversity. However, its impacts on native plant species, especially in pasture communities, are less known. Given parthenium weed causes substantial losses to Australian pastures' productivity, it is crucial to estimate its impact on pasture communities. This study evaluates the impact of parthenium weed upon species diversity in a pasture community at Kilcoy, south east Queensland, Australia. Sub-sites containing three levels of parthenium weed density (i.e. high, low and zero) were chosen to quantify the above- and below-ground plant community structure. Species richness, diversity and evenness were all found to be significantly reduced as the density of parthenium weed increased; an effect was evident even when parthenium weed was present at relatively low densities (i.e. two plants m⁻²). This trend was observed in the summer season as well as in winter season when this annual weed was absent from the above-ground plant community. This demonstrates the strong impact that parthenium weed has upon the community composition and functioning throughout the year. It also shows the long-term impact of parthenium weed on the soil seed bank where it had displaced several native species. So, management options used for parthenium weed should also consider the reduction of parthenium weed seed bank along with controlling its above-ground populations.

from Enviromental via alkiviadis.1961 on Inoreader http://ift.tt/2xEdpGQ

Perceived effectiveness rating scales applied to insomnia help-seeking messages for middle-aged Japanese people: a validity and reliability study

Abstract

Background

Communicating health messages is an important way to influence people's behaviors towards health issues. Providers need to incorporate audience's perspective to design more persuasive messages. This study aimed to develop rating scales for measuring audience's perception of effectiveness of health messages in Japanese people.

Methods

The comprehensibility scale including five items and the persuasiveness scale including seven items were designed based on literature review. A cross-sectional web-based survey was conducted among Japanese adults aged 35–45 years to assess the reliability and validity of the scales. Participants were asked to rate a text message that encouraged help-seeking intention for insomnia. All scale items were scored on a 1-to-5 point Likert scale, and they were averaged to produce an overall score for each scale.

Results

Explanatory factor analysis revealed a two-factor solution that agreed with the comprehensibility and persuasiveness scales, respectively. Correlation coefficients between each set of items ranged between 0.63–0.87 for the comprehensibility scale and 0.37–0.76 for the persuasiveness scale. Cronbach alpha (0.88) indicated satisfactory internal consistency of the set of items. The mean (SD) of the comprehensibility and persuasiveness scores were 3.70 (0.82) and 3.15 (0.61), respectively, without ceiling or floor effects. These scores were significantly associated with intended future use of the message. The proportion of participants who reported a positive help-seeking intention for insomnia was significantly higher in the higher score groups for both scales. Multiple logistic regression analysis showed that the comprehensibility and persuasiveness scores were significantly associated with the help-seeking intention for insomnia.

Conclusion

The proposed rating scales exhibited adequate reliability and validity for measuring the comprehensibility and persuasiveness of insomnia health-seeking message in middle-aged Japanese people. Further studies are needed to confirm the generalizability of the results, but these scales may be useful for pretesting a health message with audience members to make it more acceptable and persuasive to the intended audience.

Trial registration

Not applicable; this is not a report of intervention trial.

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Waste rice straw and coal fly ash composite as a novel sustainable catalytic particle electrode for strengthening oxidation of azo dyes containing wastewater in electro-Fenton process

Abstract

A novel catalytic particle electrode (CPE) was synthesized from waste rice straw and coal fly ash which was employed to strengthen electro-Fenton treating actual azo dyes containing wastewater. Results showed that the prepared CPE exhibited excellent electro-catalytic activity and significantly improved performance of pollutants removal at near-neutral pH condition, achieving over 73.5 and 90.5% of chemical oxygen demand (COD) and color removal percentages, respectively, allowing discharge criteria to be met. And the electro-Fenton with CPE improved the biodegradability of wastewater in terms of BOD₅/COD, resazurin dehydrogenase activity, and toxicity, indicating the potential application of integrated biosystem for this type of wastewater. On the basis of inhibition of different radical scavengers and fluorescence test, it was deduced that the main contribution of the novel CPE was responsible for catalyzing electro-generate H₂O₂ to produce more hydroxyl radicals in electro-Fenton, and the positive role of generation of superoxide anion at near-neutral pH was also proved, further the possible reaction mechanism was proposed. Moreover, CPE showed the advantages of superior stability and low cost at successive runs and the results offered new insights for sustainable use of waste materials.

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Mutagenic and genotoxic effects and metal contaminations in fish of the Amambai River, Upper Paraná River, Brazil

Abstract

The present study evaluated mutagenic and genotoxic effects and metal accumulation in the liver and musculature of Pterygoplichthys ambrosetti and Prochilodus lineatus in the Amambai River, a tributary of the Upper Paraná River in Brazil. We also evaluated the potential for these fish species as environmental bioindicators and performed risk assessment for conservation purposes. We found that P. ambrosetti had a higher frequency of micronuclei compared to P. lineatus (p < 0.0001). There were no significant differences between species in other erythrocyte nuclear abnormalities (ENA) (p > 0.05). For both species, the liver contained a higher concentration of metals (Cd, Pb, Cr, Cu, Fe, Zn, and Ni) than the musculature did (p < 0.0001). Of the two species, P. ambrosetti was more suitable to evaluate mutagenic and genotoxic effects and metal accumulation in the liver and musculature, likely due to its resident behavior; hence, we highlight the potential of this species for use as an environmental bioindicator. The concentrations of non-essential metals observed in the fish confirm conditions of environmental stress in the Amambai River, possibly related to the discharge of pollutants and exacerbated by lack of native vegetation cover along the watercourse.

from Enviromental via alkiviadis.1961 on Inoreader http://ift.tt/2hB3Fqk

Transcriptomic responses of the endangered freshwater mussel Margaritifera margaritifera to trace metal contamination in the Dronne River, France

Abstract

The freshwater pearl mussel Margaritifera margaritifera is one of the most threatened freshwater bivalves worldwide. In this study, we aimed (i) to study the processes by which water quality might affect freshwater mussels in situ and (ii) to provide insights into the ecotoxicological significance of water pollution to natural populations in order to provide necessary information to enhance conservation strategies. M. margaritifera specimens were sampled in two close sites located upstream or downstream from an illegal dumping site. The renal transcriptome of these animals was assembled and gene transcription determined by RNA-seq. Correlations between transcription levels of each single transcript and the bioaccumulation of nine trace metals, age (estimated by sclerochronology), and condition index were determined in order to identify genes likely to respond to a specific factor. Amongst the studied metals, Cr, Zn, Cd, and Ni were the main factors correlated with transcription levels, with effects on translation, apoptosis, immune response, response to stimulus, and transport pathways. However, the main factor explaining changes in gene transcription appeared to be the age of individuals with a negative correlation with the transcription of retrotransposon-related genes. To investigate this effect further, mussels were classified into three age classes. In young, middle-aged and old animals, transcription levels were mainly explained by Cu, Zn and age, respectively. This suggests differences in the molecular responses of this species to metals during its lifetime that must be better assessed in future ecotoxicology studies.

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Occurrence and source identification of perfluoroalkyl acids (PFAAs) in the Metedeconk River Watershed, New Jersey

Abstract

The Brick Township Municipal Utilities Authority (BTMUA), which relies on the Metedeconk River as its primary source of water supply, initiated a perfluoroalkyl acid (PFAA) source trackdown study in collaboration with the New Jersey Department of Environmental Protection (NJDEP) after discovering that the concentration of one PFAA, perfluorooctanoic acid (PFOA), was elevated at their raw surface water intake. Water samples were collected over eight sampling events between September 2011 and July 2014. Samples included surface water, groundwater, stormwater, sanitary sewer water, and commercial/industrial process water. Each sample was analyzed for ten PFAAs. Results from a set of samples collected from the 80 km² South Branch Metedeconk River watershed directed the focus of this study to a 7.5-km² area of interest. Within this area, a high concentration of PFAA contamination was documented in a localized zone. Subsequent groundwater sampling led to the identification of a plume of groundwater contamination emanating from an industrial/business park. The suspected source of PFAA detected in the river and drinking water intake was identified to a small industrial facility that used materials containing PFOA. Groundwater PFOA concentrations as high as 70,000 ng/L were found in samples taken within 200 m of the parcel and surface water concentrations as high as 130 ng/L were observed in the river. While various PFAAs were detected in the samples, particularly in groundwater samples, PFOA was identified as the primary contaminant of concern with respect to the river and the BTMUA water supply.

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Enhancement of anaerobic digestibility of waste activated sludge using photo-Fenton pretreatment

Abstract

Biological treatments, such as activated sludge process, are common methods to treat municipal and industrial wastewaters. However, they produce huge amounts of waste activated sludge (WAS). The excess sludge treatment and disposal are a challenge for wastewater treatment plants due to economic, environmental, and regulatory factors. In this study, photo-Fenton pretreatment (oxidation using hydrogen peroxide and iron catalyst aided with UV light) was optimized using response surface methodology (RSM) and central composite design (CCD) to determine the effects of three operating parameters (H₂O₂ dosage, H₂O₂/Fe²⁺ molar ratio, and irradiation time) on disintegration and dewaterability of WAS. MLVSS removal, capillary suction time (CST) reduction, sCOD, and EPS were obtained as 70%, 25%, 12,000 mg/L, and 500 mg/L, respectively, at the optimal conditions, i.e., 725 g H₂O₂/kg TS, H₂O₂/Fe²⁺ molar ratio 80, and irradiation time 40 min. Two batch-fed completely mixed mesophilic anaerobic digesters were then operated at 15-day solid retention time (SRT) and 37 ± 0.5 °C to compare the digestibility of untreated and photo-Fenton pretreated sludge in terms of volatile solids (VS) reduction, COD removal, and biogas production at steady-state operations. Photo-Fenton pretreatment followed by anaerobic digestion of WAS was very effective and yielded 75.7% total VS reduction, 81.5% COD removal, and 0.29–0.31 m³/kg VS_fed·d biogas production rate, compared to 40.7% total VS solid reduction, 54.7% COD removal, and 0.12–0.17 m³/kg VS_fed·d biogas production rate for control. Thus, photo-Fenton can be a useful pretreatment step in sludge management.

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A study on removing nitrogen from paddy field rainfall runoff by an ecological ditch–zeolite barrier system

Abstract

Ecological ditches and zeolite have been widely applied in the removal of farmland nonpoint source pollution separately; little research has been done on the effects of combining the two methods. Specifically, few studies have focused on the in situ regeneration of zeolite. A 2-year field experiment using an ecological ditch–zeolite barrier system was conducted in a paddy field of summer rice–winter wheat rotation in the Taihu Lake area. The system consisted of two zeolite barriers positioned at one third and two thirds of the length of the ditch. This study focused on the effect of the system on in situ nitrogen removal during the rice-growing season. Simultaneous laboratory kinetics experiments with natural zeolite and a series of adsorbed zeolites taken from the ditch at different time were also conducted. The concentration removal efficiencies of total nitrogen are averaged 24.66% in 2014 and 30.39% in 2015. Meanwhile, the cumulative adsorption quantity of ammonia nitrogen by the two barriers accounted for 49.27% of the ammonia nitrogen removed in 2014 and 54.35% of that in 2015. The amount of nitrogen adsorbed by plants was larger than that adsorbed by zeolite. The breakthrough curves of the zeolite and the characteristics of the zeolite surface structures from different periods all demonstrated that the zeolite can be regenerated in situ in the case of unsaturated zeolite within the ecological ditch. It can be concluded that an ecological ditch–zeolite barrier system is a realistic option for removing nitrogen from agricultural rainfall runoff in the Taihu Lake area.

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The effect of vitamin E, l -carnitine, and ginger on production traits, immune response, and antioxidant status in two broiler strains exposed to chronic heat stress

Abstract

The present study was designed to find the effect of natural and synthetic antioxidants on the performance of two broiler strains under high ambient temperature. A total of 320 day-old chicks of Hubbard and Cobb were reared for a period for 21 days under the same nutritional and management systems. On day 21 onward, one subgroup was kept as control while other subgroups were provided with vitamin E (250 mg/kg), ginger (2 g/kg), and l-carnitine (500 mg/kg) in basal diets. Body weight and feed conversion ratio (FCR) were significantly (P < 0.05) high in vitamin E-supplemented birds, while feed intake was significantly (P < 0.05) higher in l-carnitine supplemented birds irrespective of the strain. Antibody titer against infectious bursal disease (IBD) and paraoxonase (PON1) was significantly (P < 0.05) higher in vitamin E-supplemented birds compared to the other treatments. The number of heterophils and toal oxidant status (TOS) were significantly (P < 0.05) lower in vitamin E-supplemented birds. Blood glucose was significantly (P < 0.05) lower in vitamin E-supplemented birds, while total protein was significantly (P < 0.05) higher in vitamin E-supplemented group. In conclusion, the supplementation of vitamin E at the rate of 250 mg/kg improved the antioxidant status and immune response in the two broiler strains. Further, the two strains perform similarly in terms of performance and other health status parameters with no significant difference.

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Utilization of calcium-based and aluminum-based materials for the treatment of stabilized landfill leachate: a comparative study

Abstract

This study explored the efficiencies and mechanisms of refractory organic matters removal in the stabilized landfill leachate by adding different reagents. Calcium-based and aluminum-based materials were added into the leachate as comparing experiments. XRD, FTIR, and EEM were adopted to analyze the solid products and leachate. As a result, the in situ synthesized CaAl-LDHs were more beneficial for refractory organic matters removal, especially for benzodiazepines. When CaAl-LDHs were formed, the removal efficiencies of COD, UV254, and TOC were best and achieved 58.48, 81.22, and 71.30%, respectively. For fluorescent substances, humic acid-like and fulvic acid-like compounds were efficiently removed by CaAl-LDHs. In particular, CaAl-LDHs had selective removal effects on fulvic acid-like compounds, which were characteristic of small molecular weight and major carboxyl groups.

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Possible effects of melatonin against rat uterus exposure to bisphenol A during neonatal period

Abstract

The aim of this study was to investigate the possible effects of melatonin on rat uterine tissue against exposure with bisphenol A (BPA) in the neonatal period. Twenty-four female rats were divided into four groups, (n=6) per group. Group I was used as a control (sesame oil + ethanol), group II was injected daily with (100 mg/kg) BPA by subcutaneously (sc) daily postnatal days (PND 0–10), group III was injected daily with (10 mg/kg) melatonin by sc for 10 days (PND 20–30), and group IV was injected daily with (100 mg/kg) BPA (PND 0–10) and (10 mg/kg) melatonin (PND 20–30). All rats were sacrificed in the same day of metestrus cycle, approximately PND 70. Histological analyses, immunostaining of B cell lymphoma 2 (Bcl-2), and cytochrome c and TUNEL assays were performed. According to our results, neonatal exposure to BPA accelerates onset of puberty, causes degenerative and morphometric changes on rat uterus, and increases apoptotic reaction rates. The immunoreactivity of Bcl-2 was decreased after BPA administration. In addition, immunoreactivity of Bcl-2 showed an increase after melatonin treatment. However, cytochrome c immunoreactivity was decreased after melatonin administration. Our results suggest that melatonin may have positive effects against BPA-induced degenerative changes on rat uterus.

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